Controlling the hydrogenolysis of silica-supported tungsten pentamethyl leads to a class of highly electron deficient partially alkylated metal hydrides

The well-defined single-site silica-supported tungsten complex [([triple bond, length as m-dash]Si–O–)W(Me)(5)], 1, is an excellent precatalyst for alkane metathesis. The unique structure of 1 allows the synthesis of unprecedented tungsten hydrido methyl surface complexes via a controlled hydrogenol...

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Detalles Bibliográficos
Autores principales: Maity, Niladri, Barman, Samir, Callens, Emmanuel, Samantaray, Manoja K., Abou-Hamad, Edy, Minenkov, Yury, D'Elia, Valerio, Hoffman, Adam S., Widdifield, Cory M., Cavallo, Luigi, Gates, Bruce C., Basset, Jean-Marie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5964938/
https://www.ncbi.nlm.nih.gov/pubmed/29899899
http://dx.doi.org/10.1039/c5sc03490f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5964938/
https://www.ncbi.nlm.nih.gov/pubmed/29899899
http://dx.doi.org/10.1039/c5sc03490f

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