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Supramolecular trap for a transient corannulene trianion
The first structural characterization of the transient triply-reduced state of corannulene (C(20)H(10)) is accomplished. The X-ray crystallographic study reveals that the C(20)H(10)˙(3–) trianions, generated by corannulene reduction with metallic cesium, form a novel type of supramolecular sandwich-...
Autores principales: | Zabula, Alexander V., Spisak, Sarah N., Filatov, Alexander S., Rogachev, Andrey Yu., Clérac, Rodolphe, Petrukhina, Marina A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5966907/ https://www.ncbi.nlm.nih.gov/pubmed/29899919 http://dx.doi.org/10.1039/c5sc04385a |
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