Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?

A library of water-soluble dynamic single-chain polymeric nanoparticles (SCPN) was prepared using a controlled radical polymerisation technique followed by the introduction of functional groups, including probes at targeted positions. The combined tools of electron paramagnetic resonance (EPR) and O...

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Detalles Bibliográficos
Autores principales: Stals, Patrick J. M., Cheng, Chi-Yuan, van Beek, Lotte, Wauters, Annelies C., Palmans, Anja R. A., Han, Songi, Meijer, E. W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5968450/
https://www.ncbi.nlm.nih.gov/pubmed/29899925
http://dx.doi.org/10.1039/c5sc02319j
Descripción
Sumario:A library of water-soluble dynamic single-chain polymeric nanoparticles (SCPN) was prepared using a controlled radical polymerisation technique followed by the introduction of functional groups, including probes at targeted positions. The combined tools of electron paramagnetic resonance (EPR) and Overhauser dynamic nuclear polarization (ODNP) reveal that these SCPNs have structural and surface hydration properties resembling that of enzymes.

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