Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?

A library of water-soluble dynamic single-chain polymeric nanoparticles (SCPN) was prepared using a controlled radical polymerisation technique followed by the introduction of functional groups, including probes at targeted positions. The combined tools of electron paramagnetic resonance (EPR) and O...

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Autores principales: Stals, Patrick J. M., Cheng, Chi-Yuan, van Beek, Lotte, Wauters, Annelies C., Palmans, Anja R. A., Han, Songi, Meijer, E. W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5968450/
https://www.ncbi.nlm.nih.gov/pubmed/29899925
http://dx.doi.org/10.1039/c5sc02319j
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author Stals, Patrick J. M.
Cheng, Chi-Yuan
van Beek, Lotte
Wauters, Annelies C.
Palmans, Anja R. A.
Han, Songi
Meijer, E. W.
author_facet Stals, Patrick J. M.
Cheng, Chi-Yuan
van Beek, Lotte
Wauters, Annelies C.
Palmans, Anja R. A.
Han, Songi
Meijer, E. W.
author_sort Stals, Patrick J. M.
collection PubMed
description A library of water-soluble dynamic single-chain polymeric nanoparticles (SCPN) was prepared using a controlled radical polymerisation technique followed by the introduction of functional groups, including probes at targeted positions. The combined tools of electron paramagnetic resonance (EPR) and Overhauser dynamic nuclear polarization (ODNP) reveal that these SCPNs have structural and surface hydration properties resembling that of enzymes.
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spelling pubmed-59684502018-06-13 Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function? Stals, Patrick J. M. Cheng, Chi-Yuan van Beek, Lotte Wauters, Annelies C. Palmans, Anja R. A. Han, Songi Meijer, E. W. Chem Sci Chemistry A library of water-soluble dynamic single-chain polymeric nanoparticles (SCPN) was prepared using a controlled radical polymerisation technique followed by the introduction of functional groups, including probes at targeted positions. The combined tools of electron paramagnetic resonance (EPR) and Overhauser dynamic nuclear polarization (ODNP) reveal that these SCPNs have structural and surface hydration properties resembling that of enzymes. Royal Society of Chemistry 2016-03-01 2015-12-08 /pmc/articles/PMC5968450/ /pubmed/29899925 http://dx.doi.org/10.1039/c5sc02319j Text en This journal is © The Royal Society of Chemistry 2016 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Stals, Patrick J. M.
Cheng, Chi-Yuan
van Beek, Lotte
Wauters, Annelies C.
Palmans, Anja R. A.
Han, Songi
Meijer, E. W.
Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?
title Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?
title_full Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?
title_fullStr Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?
title_full_unstemmed Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?
title_short Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?
title_sort surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5968450/
https://www.ncbi.nlm.nih.gov/pubmed/29899925
http://dx.doi.org/10.1039/c5sc02319j
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