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Redox-ligand sustains controlled generation of CF(3) radicals by well-defined copper complex

A well-defined copper complex bearing iminosemiquinone ligands performs single electron reduction of an electrophilic CF(3)(+) source into CF˙3 radicals. This redox behavior is enabled by the ligand which shuttles through two different redox states (iminosemiquinone and iminobenzoquinone) while the...

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Detalles Bibliográficos
Autores principales:	Jacquet, Jérémy, Blanchard, Sébastien, Derat, Etienne, Desage-El Murr, Marine, Fensterbank, Louis
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5968567/ https://www.ncbi.nlm.nih.gov/pubmed/29899928 http://dx.doi.org/10.1039/c5sc03636d

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