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An Incomplete Spin Transition Associated with a Z′=1→Z′=24 Crystallographic Symmetry Breaking
Crystalline [FeL (2)][BF(4)](2) ⋅Me(2)CO (L=N‐[2,6‐di{pyrazol‐1‐yl}pyrid‐4‐yl]acetamide) is high‐spin at room temperature, and undergoes an abrupt, hysteretic spin‐crossover at T [Formula: see text] =137 K (ΔT [Formula: see text] =14 K) that proceeds to about 50 % completeness. This is associated wi...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5972820/ https://www.ncbi.nlm.nih.gov/pubmed/29111607 http://dx.doi.org/10.1002/chem.201704896 |