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Quantitative model for rationalizing solvent effect in noncovalent CH–Aryl interactions

The strength of CH–aryl interactions (ΔG) in 14 solvents was determined via the conformational analysis of a molecular torsion balance. The molecular balance adopted folded and unfolded conformers in which the ratio of the conformers in solution provided a quantitative measure of ΔG as a function of...

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Detalles Bibliográficos
Autores principales:	Emenike, Bright U., Bey, Sara N., Bigelow, Brianna C., Chakravartula, Srinivas V. S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5975927/ https://www.ncbi.nlm.nih.gov/pubmed/29910898 http://dx.doi.org/10.1039/c5sc03550c

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