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Water opens the door to organolithiums and Grignard reagents: exploring and comparing the reactivity of highly polar organometallic compounds in unconventional reaction media towards the synthesis of tetrahydrofurans

It has always been a firm conviction of the scientific community that the employment of both anhydrous conditions and water-free reaction media is required for the successful handling of organometallic compounds with highly polarised metal–carbon bonds. Herein, we describe how, under heterogeneous c...

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Detalles Bibliográficos
Autores principales: Cicco, Luciana, Sblendorio, Stefania, Mansueto, Rosmara, Perna, Filippo M., Salomone, Antonio, Florio, Saverio, Capriati, Vito
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5975938/
https://www.ncbi.nlm.nih.gov/pubmed/29910874
http://dx.doi.org/10.1039/c5sc03436a