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In Situ Formation of AgCo Stabilized on Graphitic Carbon Nitride and Concomitant Hydrolysis of Ammonia Borane to Hydrogen
The development of highly-efficient heterogeneous supported catalysts for catalytic hydrolysis of ammonia borane to yield hydrogen is of significant importance considering the versatile usages of hydrogen. Herein, we reported the in situ synthesis of AgCo bimetallic nanoparticles supported on g-C(3)...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5977294/ https://www.ncbi.nlm.nih.gov/pubmed/29701660 http://dx.doi.org/10.3390/nano8050280 |
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author | Wang, Qi Xu, Caili Ming, Mei Yang, Yingchun Xu, Bin Wang, Yi Zhang, Yun Wu, Jie Fan, Guangyin |
author_facet | Wang, Qi Xu, Caili Ming, Mei Yang, Yingchun Xu, Bin Wang, Yi Zhang, Yun Wu, Jie Fan, Guangyin |
author_sort | Wang, Qi |
collection | PubMed |
description | The development of highly-efficient heterogeneous supported catalysts for catalytic hydrolysis of ammonia borane to yield hydrogen is of significant importance considering the versatile usages of hydrogen. Herein, we reported the in situ synthesis of AgCo bimetallic nanoparticles supported on g-C(3)N(4) and concomitant hydrolysis of ammonia borane for hydrogen evolution at room temperature. The as-synthesized Ag(0.1)Co(0.9)/g-C(3)N(4) catalysts displayed the highest turnover frequency (TOF) value of 249.02 mol H(2)·(mol(Ag)·min)(−1) for hydrogen evolution from the hydrolysis of ammonia borane, which was higher than many other reported values. Furthermore, the Ag(0.1)Co(0.9)/g-C(3)N(4) catalyst could be recycled during five consecutive runs. The study proves that Ag(0.1)Co(0.9)/g-C(3)N(4) is a potential catalytic material toward the hydrolysis of ammonia borane for hydrogen production. |
format | Online Article Text |
id | pubmed-5977294 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-59772942018-06-05 In Situ Formation of AgCo Stabilized on Graphitic Carbon Nitride and Concomitant Hydrolysis of Ammonia Borane to Hydrogen Wang, Qi Xu, Caili Ming, Mei Yang, Yingchun Xu, Bin Wang, Yi Zhang, Yun Wu, Jie Fan, Guangyin Nanomaterials (Basel) Article The development of highly-efficient heterogeneous supported catalysts for catalytic hydrolysis of ammonia borane to yield hydrogen is of significant importance considering the versatile usages of hydrogen. Herein, we reported the in situ synthesis of AgCo bimetallic nanoparticles supported on g-C(3)N(4) and concomitant hydrolysis of ammonia borane for hydrogen evolution at room temperature. The as-synthesized Ag(0.1)Co(0.9)/g-C(3)N(4) catalysts displayed the highest turnover frequency (TOF) value of 249.02 mol H(2)·(mol(Ag)·min)(−1) for hydrogen evolution from the hydrolysis of ammonia borane, which was higher than many other reported values. Furthermore, the Ag(0.1)Co(0.9)/g-C(3)N(4) catalyst could be recycled during five consecutive runs. The study proves that Ag(0.1)Co(0.9)/g-C(3)N(4) is a potential catalytic material toward the hydrolysis of ammonia borane for hydrogen production. MDPI 2018-04-26 /pmc/articles/PMC5977294/ /pubmed/29701660 http://dx.doi.org/10.3390/nano8050280 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Wang, Qi Xu, Caili Ming, Mei Yang, Yingchun Xu, Bin Wang, Yi Zhang, Yun Wu, Jie Fan, Guangyin In Situ Formation of AgCo Stabilized on Graphitic Carbon Nitride and Concomitant Hydrolysis of Ammonia Borane to Hydrogen |
title | In Situ Formation of AgCo Stabilized on Graphitic Carbon Nitride and Concomitant Hydrolysis of Ammonia Borane to Hydrogen |
title_full | In Situ Formation of AgCo Stabilized on Graphitic Carbon Nitride and Concomitant Hydrolysis of Ammonia Borane to Hydrogen |
title_fullStr | In Situ Formation of AgCo Stabilized on Graphitic Carbon Nitride and Concomitant Hydrolysis of Ammonia Borane to Hydrogen |
title_full_unstemmed | In Situ Formation of AgCo Stabilized on Graphitic Carbon Nitride and Concomitant Hydrolysis of Ammonia Borane to Hydrogen |
title_short | In Situ Formation of AgCo Stabilized on Graphitic Carbon Nitride and Concomitant Hydrolysis of Ammonia Borane to Hydrogen |
title_sort | in situ formation of agco stabilized on graphitic carbon nitride and concomitant hydrolysis of ammonia borane to hydrogen |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5977294/ https://www.ncbi.nlm.nih.gov/pubmed/29701660 http://dx.doi.org/10.3390/nano8050280 |
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