A Hollow-Structured Manganese Oxide Cathode for Stable Zn-MnO(2) Batteries

Aqueous rechargeable zinc-manganese dioxide (Zn-MnO(2)) batteries are considered as one of the most promising energy storage devices for large scale-energy storage systems due to their low cost, high safety, and environmental friendliness. However, only a few cathode materials have been demonstrated to achieve stable cycling for aqueous rechargeable Zn-MnO(2) batteries. Here, we report a new material consisting of hollow MnO(2) nanospheres, which can be used for aqueous Zn-MnO(2) batteries. The hollow MnO(2) nanospheres can achieve high specific capacity up to ~405 mAh g(−1) at 0.5 C. More importantly, the hollow structure of birnessite-type MnO(2) enables long-term cycling stability for the aqueous Zn-MnO(2) batteries. The excellent performance of the hollow MnO(2) nanospheres should be due to their unique structural properties that enable the easy intercalation of zinc ions.