Fabrication Flexible and Luminescent Nanofibrillated Cellulose Films with Modified SrAl(2)O(4): Eu, Dy Phosphors via Nanoscale Silica and Aminosilane

Flexible 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-oxidized nanofibrillated cellulose (ONFC) films with long afterglow luminescence containing modified SrAl(2)O(4): Eu(2+), Dy(3+) (SAOED) phosphors were fabricated by a template method. Tetraethyl orthosilicate (TEOS) and (3-aminopropyl) trimethoxy-silane (APTMS) were employed cooperatively to improve the water resistance and compatibility of the SAOED particles in the ONFC suspension. The structure and morphology after modification evidenced the formation of a superior SiO(2) layer and coarse amino-compounds on the surface of the phosphors. Homogeneous dispersions containing ONFC and the modified phosphors were prepared and the interface of composite films containing the amino-modified particles showed a more closely packed structure and had less voids at the interface between the cellulose and luminescent particles than that of silica-modified phosphors. The emission spectra for luminescent films showed a slight blue shift (3.2 nm) at around 512 nm. Such flexible films with good luminescence, thermal resistance, and mechanical properties can find applications in fields like luminous flexible equipment, night indication, and portable logo or labels.