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EPDM Rubber Modified by Nitrogen Plasma Immersion Ion Implantation

Ethylene-propylene diene monomer rubber (EPDM) was treated by plasma immersion ion implantation (PIII) with nitrogen ions of 20 keV energy and fluence from 10(13) to 10(16) ions/cm(2). The Fourier-transform infrared attenuated total reflection spectra, atomic force microscopy and optical microscopy...

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Detalles Bibliográficos
Autor principal: Kondyurin, Alexey
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5978034/
https://www.ncbi.nlm.nih.gov/pubmed/29695109
http://dx.doi.org/10.3390/ma11050657
Descripción
Sumario:Ethylene-propylene diene monomer rubber (EPDM) was treated by plasma immersion ion implantation (PIII) with nitrogen ions of 20 keV energy and fluence from 10(13) to 10(16) ions/cm(2). The Fourier-transform infrared attenuated total reflection spectra, atomic force microscopy and optical microscopy showed significant structure changes of the surface. The analysis of an interface of PIII treated EPDM rubber with polyurethane binder showed a cohesive character of the adhesion joint fracture at the presence of solvent and interpreted as covalent bond network formation between the PIII treated rubber and the adhesive.