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Silylation reactions on nanoporous gold via homolytic Si–H activation of silanes

Si–H bond activation is an important process implicated in many useful synthetic applications including silylation and transfer hydrogenation reactions. Herein we discovered homolytic activation of Si–H bonds on the surface of nanoporous gold (NPG), forming hydrogen radicals and [Au]–[Si] intermedia...

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Detalles Bibliográficos
Autores principales:	Li, Hongbo, Guo, Huifang, Li, Zhiwen, Wu, Cai, Li, Jing, Zhao, Chunliang, Guo, Shuangxi, Ding, Yi, He, Wei, Li, Yadong
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5982200/ https://www.ncbi.nlm.nih.gov/pubmed/29910932 http://dx.doi.org/10.1039/c8sc01427b

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