Cargando…
Modified α,α′-trehalose and d-glucose: green monomers for the synthesis of vinyl copolymers
Allyl saccharide/vinyl copolymers were synthesized using renewable feedstocks (α,α′-trehalose and d-glucose) to obtain ‘green monomers’. Properly designed synthetic procedures were used to obtain copolymers with high purity and without protection/deprotection steps in agreement with the principles o...
Autores principales: | , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society Publishing
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5990774/ https://www.ncbi.nlm.nih.gov/pubmed/29892349 http://dx.doi.org/10.1098/rsos.171313 |
_version_ | 1783329644406112256 |
---|---|
author | Papacchini, A. Telaretti Leggieri, M. R. Zucchini, L. Ortenzi, M. A. Ridi, F. Giomi, D. Salvini, A. |
author_facet | Papacchini, A. Telaretti Leggieri, M. R. Zucchini, L. Ortenzi, M. A. Ridi, F. Giomi, D. Salvini, A. |
author_sort | Papacchini, A. |
collection | PubMed |
description | Allyl saccharide/vinyl copolymers were synthesized using renewable feedstocks (α,α′-trehalose and d-glucose) to obtain ‘green monomers’. Properly designed synthetic procedures were used to obtain copolymers with high purity and without protection/deprotection steps in agreement with the principles of green chemistry and industrial sustainability. The use of saccharide derivatives as monomers allowed products to be obtained that showed high affinity and compatibility for the cellulosic substrates, like paper or wood, and that were suitable for applications like adhesion or consolidation in the field of cultural heritage. All reaction products were characterized by FT-IR and NMR spectroscopies and SEC analyses, while thermal properties were evaluated by DSC analyses. |
format | Online Article Text |
id | pubmed-5990774 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | The Royal Society Publishing |
record_format | MEDLINE/PubMed |
spelling | pubmed-59907742018-06-11 Modified α,α′-trehalose and d-glucose: green monomers for the synthesis of vinyl copolymers Papacchini, A. Telaretti Leggieri, M. R. Zucchini, L. Ortenzi, M. A. Ridi, F. Giomi, D. Salvini, A. R Soc Open Sci Chemistry Allyl saccharide/vinyl copolymers were synthesized using renewable feedstocks (α,α′-trehalose and d-glucose) to obtain ‘green monomers’. Properly designed synthetic procedures were used to obtain copolymers with high purity and without protection/deprotection steps in agreement with the principles of green chemistry and industrial sustainability. The use of saccharide derivatives as monomers allowed products to be obtained that showed high affinity and compatibility for the cellulosic substrates, like paper or wood, and that were suitable for applications like adhesion or consolidation in the field of cultural heritage. All reaction products were characterized by FT-IR and NMR spectroscopies and SEC analyses, while thermal properties were evaluated by DSC analyses. The Royal Society Publishing 2018-05-23 /pmc/articles/PMC5990774/ /pubmed/29892349 http://dx.doi.org/10.1098/rsos.171313 Text en © 2018 The Authors. http://creativecommons.org/licenses/by/4.0/ Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited. |
spellingShingle | Chemistry Papacchini, A. Telaretti Leggieri, M. R. Zucchini, L. Ortenzi, M. A. Ridi, F. Giomi, D. Salvini, A. Modified α,α′-trehalose and d-glucose: green monomers for the synthesis of vinyl copolymers |
title | Modified α,α′-trehalose and d-glucose: green monomers for the synthesis of vinyl copolymers |
title_full | Modified α,α′-trehalose and d-glucose: green monomers for the synthesis of vinyl copolymers |
title_fullStr | Modified α,α′-trehalose and d-glucose: green monomers for the synthesis of vinyl copolymers |
title_full_unstemmed | Modified α,α′-trehalose and d-glucose: green monomers for the synthesis of vinyl copolymers |
title_short | Modified α,α′-trehalose and d-glucose: green monomers for the synthesis of vinyl copolymers |
title_sort | modified α,α′-trehalose and d-glucose: green monomers for the synthesis of vinyl copolymers |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5990774/ https://www.ncbi.nlm.nih.gov/pubmed/29892349 http://dx.doi.org/10.1098/rsos.171313 |
work_keys_str_mv | AT papacchinia modifiedaatrehaloseanddglucosegreenmonomersforthesynthesisofvinylcopolymers AT telarettileggierimr modifiedaatrehaloseanddglucosegreenmonomersforthesynthesisofvinylcopolymers AT zucchinil modifiedaatrehaloseanddglucosegreenmonomersforthesynthesisofvinylcopolymers AT ortenzima modifiedaatrehaloseanddglucosegreenmonomersforthesynthesisofvinylcopolymers AT ridif modifiedaatrehaloseanddglucosegreenmonomersforthesynthesisofvinylcopolymers AT giomid modifiedaatrehaloseanddglucosegreenmonomersforthesynthesisofvinylcopolymers AT salvinia modifiedaatrehaloseanddglucosegreenmonomersforthesynthesisofvinylcopolymers |