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Utilization of steric hindrance of alkyl lithium-based initiator to synthesize high 1,4 unit-containing hydroxyl- terminated polybutadiene

A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized. By using TBDMSODPrLi, hydroxyl-terminated polybutadiene (HTPB) was prepared via anionic polymerization. The macromolecular structu...

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Detalles Bibliográficos
Autores principales:	Min, Xin, Fan, Xiaodong, Liu, Jie
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society Publishing 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5990791/ https://www.ncbi.nlm.nih.gov/pubmed/29892450 http://dx.doi.org/10.1098/rsos.180156

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