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Copper-catalysed regioselective sulfenylation of indoles with sodium sulfinates

A copper-catalysed sulfenylation of indoles with sodium sulfinates that affords 3-sulfenylindoles in good-to-excellent yields in N,N-dimethyl formamide (DMF) is described. In the process, DMF serves not only as a solvent but also as a reductant. This transformation is easy to carry out and has mild...

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Detalles Bibliográficos
Autores principales: Luo, Xiaojun, Liu, Qiang, Zhu, Hongxia, Chen, Huoji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society Publishing 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5990840/
https://www.ncbi.nlm.nih.gov/pubmed/29892452
http://dx.doi.org/10.1098/rsos.180170