Cargando…

1,2‐Addition of Diethylzinc to a Bis(Imidazolyl)ketone Ligand

In this study, the selective 1,2‐addition of diethylzinc to the ketone functionality of BM(diPh)IK [bis(1‐methyl‐4,5‐diphenylimidazolyl)ketone] is shown. The reaction product is isolated in a dimeric form with a planar Zn(2)(µ‐O)(2)‐motif keeping the two monomers together. This compound can serve as...

Descripción completa

Detalles Bibliográficos
Autores principales:	Folkertsma, Emma, Benthem, Sanne H., Jastrzebski, Johann T. B. H., Lutz, Martin, Moret, Marc‐Etienne, Klein Gebbink, Robertus J. M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2018
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5993287/ https://www.ncbi.nlm.nih.gov/pubmed/29937689 http://dx.doi.org/10.1002/ejic.201701363

Ejemplares similares

Combination of Scanning Probe Microscopy and Coordination Chemistry: Structural and Electronic Study of Bis(methylbenzimidazolyl)ketone and Its Iron Complex
por: Folkertsma, Emma, et al.
Publicado: (2017)

Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton‐Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C−H Bond in H(2) Formation
por: Ghosh, Pradip, et al.
Publicado: (2020)

Cobalt(II) and (I) Complexes of Diphosphine‐Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions
por: Verhoeven, Dide G. A., et al.
Publicado: (2019)

Asymmetric hydrosilylation of ketones catalyzed by complexes formed from trans-diaminocyclohexane-based diamines and diethylzinc
por: Gajewy, Jadwiga, et al.
Publicado: (2012)

Structurally Modelling the 2‐His‐1‐Carboxylate Facial Triad with a Bulky N,N,O Phenolate Ligand
por: Monkcom, Emily C., et al.
Publicado: (2021)

A Cp(tt)‐Based Trioxo‐Rhenium Catalyst for the Deoxydehydration of Diols and Polyols
por: Li, Jing, et al.
Publicado: (2018)

The Solid-State Structures of Dimethylzinc and Diethylzinc
por: Bacsa, John, et al.
Publicado: (2011)

Efficient Diethylzinc/Gallic Acid and Diethylzinc/Gallic Acid Ester Catalytic Systems for the Ring-Opening Polymerization of rac-Lactide
por: Żółtowska, Karolina, et al.
Publicado: (2015)

Crystal structure of tetrakis(tetrahydrofuran-κO)bis(trifluoromethanesulfonato-κO)iron(II)
por: Riemersma, Charl F., et al.
Publicado: (2019)

Zinc complexes of the biomimetic N,N,O ligand family of substituted 3,3-bis(1-alkylimidazol-2-yl)propionates: the formation of oxalate from pyruvate
por: Bruijnincx, Pieter C. A., et al.
Publicado: (2007)

Imidazolyl activated carbon refluxed with ethanediamine as reusable heterogeneous catalysts for Michael addition
por: Liu, Wenzhu, et al.
Publicado: (2018)

Copper(II) Complexes of Amino Acids and Peptides Containing Chelating bis(imidazolyl) Residues
por: Sóvágó, lmre, et al.
Publicado: (2003)

Nickel is a Different Pickle: Trends in Water Oxidation Catalysis for Molecular Nickel Complexes
por: Hessels, Joeri, et al.
Publicado: (2020)

Design and Synthesis of Novel Bis-Imidazolyl Phenyl Butadiyne Derivatives as HCV NS5A Inhibitors
por: Hamdy, Jehad, et al.
Publicado: (2022)

Excited state dynamics for visible-light sensitization of a photochromic benzil-subsituted phenoxyl-imidazolyl radical
por: Kobayashi, Yoichi, et al.
Publicado: (2019)

Combined experimental and theoretical studies of regio- and stereoselectivity in reactions of β-isoxazolyl- and β-imidazolyl enamines with nitrile oxides
por: Efimov, Ilya V, et al.
Publicado: (2016)

Synthesis of asymmetric [bis(imidazolyl)-BH(2)](+)-cation-based ionic liquids as potential rocket fuels
por: Li, Xue, et al.
Publicado: (2021)

Primary-tertiary diamine-catalyzed Michael addition of ketones to isatylidenemalononitrile derivatives
por: Kumar, Akshay, et al.
Publicado: (2014)

Addition of dithi(ol)anylium tetrafluoroborates to α,β-unsaturated ketones
por: Huang, Yu-Chieh, et al.
Publicado: (2018)

Application of Diethylzinc/Propyl Gallate Catalytic System for Ring-Opening Copolymerization of rac-Lactide and ε-Caprolactone
por: Wyrębiak, Rafał, et al.
Publicado: (2019)

Chemical reaction-transport model of oxidized diethylzinc based on quantum mechanics and computational fluid dynamics approaches
por: Li, Jian, et al.
Publicado: (2018)

Combining metal–metal cooperativity, metal–ligand cooperativity and chemical non-innocence in diiron carbonyl complexes
por: van Beek, Cody B., et al.
Publicado: (2022)

Hydrogen Evolution Electrocatalysis with a Molecular Cobalt Bis(alkylimidazole)methane Complex in DMF: a Critical Activity Analysis
por: de Vos, Sander D., et al.
Publicado: (2022)

Synthesis and Biological Evaluation of Novel Alkyl-Imidazolyl Carbinols and their Esters: Potent Antimycotics
por: Krauss, Jürgen, et al.
Publicado: (2013)

Design, Synthesis and Evaluation of Antitubercular Activity of Novel Dihydropyridine Containing Imidazolyl Substituent
por: Iman, Maryam, et al.
Publicado: (2015)

Lipid Membrane Adsorption Determines Photodynamic Efficiency of β-Imidazolyl-Substituted Porphyrins
por: Jiménez-Munguía, Irene, et al.
Publicado: (2019)

Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids
por: Hou, Peng, et al.
Publicado: (2023)

Macrocyclic bis(ureas) as ligands for anion complexation
por: Kretschmer, Claudia, et al.
Publicado: (2014)

Different molecular conformations in the crystal structures of three 5-nitroimidazolyl derivatives
por: Osorio, Luis F. B., et al.
Publicado: (2018)

Directed Lithiation of Protected 4-Chloropyrrolopyrimidine: Addition to Aldehydes and Ketones Aided by Bis(2-dimethylaminoethyl)ether
por: Bjørnstad, Frithjof, et al.
Publicado: (2023)

Synthesis of N-Heterocycle Substituted Silyl Ligands within the Coordination Sphere of Iron
por: Witteman, Léon, et al.
Publicado: (2018)

ω‐Imidazolyl‐alkyl derivatives as new preclinical drug candidates for treating non‐alcoholic steatohepatitis
por: Diesinger, Torsten, et al.
Publicado: (2021)

Site-specific functionalization with amino, guanidinium, and imidazolyl groups enabling the activation of 10–23 DNAzyme
por: Du, Shanshan, et al.
Publicado: (2020)

Construction of bis-, tris- and tetrahydrazones by addition of azoalkenes to amines and ammonia
por: Semakin, Artem N, et al.
Publicado: (2016)

Oxaphospholes and Bisphospholes from Phosphinophosphonates and α,β-Unsaturated Ketones
por: Arkhypchuk, Anna I, et al.
Publicado: (2013)

Efficient gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation of unactivated alkenes with α-ketones
por: Xiao, Ya-Ping, et al.
Publicado: (2011)

Indole-3-thiouronium nitrate
por: Lutz, Martin, et al.
Publicado: (2007)

Indole-3-thiouronium iodide
por: Lutz, Martin, et al.
Publicado: (2007)

Alkali Metal Complexes of a Bis(diphenylphosphino)methane Functionalized Amidinate Ligand: Synthesis and Luminescence
por: Zovko, Christina, et al.
Publicado: (2021)

CuCl-catalyzed aerobic oxidation of 2,3-allenols to 1,2-allenic ketones with 1:1 combination of phenanthroline and bipyridine as ligands
por: Gao, Shuxu, et al.
Publicado: (2011)

Cannot write session to /tmp/vufind_sessions/sess_561aaeg771jldb1ausupmgplf5