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Enantioselective synthesis of amines by combining photoredox and enzymatic catalysis in a cyclic reaction network
Visible light-driven reduction of imines to enantioenriched amines in aqueous solution is demonstrated for the first time. Excitation of a new water-soluble variant of the widely used [Ir(ppy)(3)] (ppy = 2-phenylpyridine) photosensitizer in the presence of a cyclic imine affords a highly reactive α-...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5994792/ https://www.ncbi.nlm.nih.gov/pubmed/29938035 http://dx.doi.org/10.1039/c8sc01561a |