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Enhancement of CO(2) binding and mechanical properties upon diamine functionalization of M(2)(dobpdc) metal–organic frameworks

The family of diamine-appended metal–organic frameworks exemplified by compounds of the type mmen–M(2)(dobpdc) (mmen = N,N′-dimethylethylenediamine; M = Mg, Mn, Fe, Co, Zn; dobpdc(4–) = 4,4′-dioxidobiphenyl-3,3′-dicarboxylate) are adsorbents with significant potential for carbon capture, due to thei...

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Detalles Bibliográficos
Autores principales: Lee, Jung-Hoon, Siegelman, Rebecca L., Maserati, Lorenzo, Rangel, Tonatiuh, Helms, Brett A., Long, Jeffrey R., Neaton, Jeffrey B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001253/
https://www.ncbi.nlm.nih.gov/pubmed/29997874
http://dx.doi.org/10.1039/c7sc05217k