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Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products
The use of electricity instead of stoichiometric amounts of oxidizers or reducing agents in synthesis is very appealing for economic and ecological reasons, and represents a major driving force for research efforts in this area. To use electron transfer at the electrode for a successful transformati...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001547/ https://www.ncbi.nlm.nih.gov/pubmed/29359378 http://dx.doi.org/10.1002/anie.201712732 |
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author | Möhle, Sabine Zirbes, Michael Rodrigo, Eduardo Gieshoff, Tile Wiebe, Anton Waldvogel, Siegfried R. |
author_facet | Möhle, Sabine Zirbes, Michael Rodrigo, Eduardo Gieshoff, Tile Wiebe, Anton Waldvogel, Siegfried R. |
author_sort | Möhle, Sabine |
collection | PubMed |
description | The use of electricity instead of stoichiometric amounts of oxidizers or reducing agents in synthesis is very appealing for economic and ecological reasons, and represents a major driving force for research efforts in this area. To use electron transfer at the electrode for a successful transformation in organic synthesis, the intermediate radical (cation/anion) has to be stabilized. Its combination with other approaches in organic chemistry or concepts of contemporary synthesis allows the establishment of powerful synthetic methods. The aim in the 21st Century will be to use as little fossil carbon as possible and, for this reason, the use of renewable sources is becoming increasingly important. The direct conversion of renewables, which have previously mainly been incinerated, is of increasing interest. This Review surveys many of the recent seminal important developments which will determine the future of this dynamic emerging field. |
format | Online Article Text |
id | pubmed-6001547 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-60015472018-06-21 Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products Möhle, Sabine Zirbes, Michael Rodrigo, Eduardo Gieshoff, Tile Wiebe, Anton Waldvogel, Siegfried R. Angew Chem Int Ed Engl Reviews The use of electricity instead of stoichiometric amounts of oxidizers or reducing agents in synthesis is very appealing for economic and ecological reasons, and represents a major driving force for research efforts in this area. To use electron transfer at the electrode for a successful transformation in organic synthesis, the intermediate radical (cation/anion) has to be stabilized. Its combination with other approaches in organic chemistry or concepts of contemporary synthesis allows the establishment of powerful synthetic methods. The aim in the 21st Century will be to use as little fossil carbon as possible and, for this reason, the use of renewable sources is becoming increasingly important. The direct conversion of renewables, which have previously mainly been incinerated, is of increasing interest. This Review surveys many of the recent seminal important developments which will determine the future of this dynamic emerging field. John Wiley and Sons Inc. 2018-04-19 2018-05-22 /pmc/articles/PMC6001547/ /pubmed/29359378 http://dx.doi.org/10.1002/anie.201712732 Text en © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
spellingShingle | Reviews Möhle, Sabine Zirbes, Michael Rodrigo, Eduardo Gieshoff, Tile Wiebe, Anton Waldvogel, Siegfried R. Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products |
title | Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products |
title_full | Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products |
title_fullStr | Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products |
title_full_unstemmed | Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products |
title_short | Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products |
title_sort | modern electrochemical aspects for the synthesis of value‐added organic products |
topic | Reviews |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001547/ https://www.ncbi.nlm.nih.gov/pubmed/29359378 http://dx.doi.org/10.1002/anie.201712732 |
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