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Silyl‐Phosphino‐Carbene Complexes of Uranium(IV)

Unprecedented silyl‐phosphino‐carbene complexes of uranium(IV) are presented, where before all covalent actinide–carbon double bonds were stabilised by phosphorus(V) substituents or restricted to matrix isolation experiments. Conversion of [U(BIPM(TMS))(Cl)(μ‐Cl)(2)Li(THF)(2)] (1, BIPM(TMS)=C(PPh(2)...

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Detalles Bibliográficos
Autores principales:	Lu, Erli, Boronski, Josef T., Gregson, Matthew, Wooles, Ashley J., Liddle, Stephen T.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2018
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001699/ https://www.ncbi.nlm.nih.gov/pubmed/29534326 http://dx.doi.org/10.1002/anie.201802080

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