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Influence of the ordering of impurities on the appearance of an energy gap and on the electrical conductance of graphene
In the one-band model of strong coupling, the influence of substitutional impurity atoms on the energy spectrum and electrical conductance of graphene is studied. It is established that the ordering of substitutional impurity atoms on nodes of the crystal lattice causes the appearance of a gap in th...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002564/ https://www.ncbi.nlm.nih.gov/pubmed/29904112 http://dx.doi.org/10.1038/s41598-018-26925-0 |
Sumario: | In the one-band model of strong coupling, the influence of substitutional impurity atoms on the energy spectrum and electrical conductance of graphene is studied. It is established that the ordering of substitutional impurity atoms on nodes of the crystal lattice causes the appearance of a gap in the energy spectrum of graphene with width η|δ| centered at the point yδ, where η is the parameter of ordering, δ is the difference of the scattering potentials of impurity atoms and carbon atoms, and y is the impurity concentration. The maximum value of the parameter of ordering is [Formula: see text] . For the complete ordering of impurity atoms, the energy gap width equals [Formula: see text] . If the Fermi level falls in the region of the mentioned gap, then the electrical conductance [Formula: see text] at the ordering of graphene, i.e., the metal–dielectric transition arises. If the Fermi level is located outside the gap, then the electrical conductance increases with the parameter of order η by the relation [Formula: see text] . At the concentration [Formula: see text] , as the ordering of impurity atoms η →1, the electrical conductance of graphene [Formula: see text] , i.e., the transition of graphene in the state of ideal electrical conductance arises. |
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