Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(4-hy­droxy­phen­yl)prop-2-en-1-one] N,N-di­methyl­formamide disolvate

In the bis­chalcone mol­ecule of the title compound, C(24)H(18)O(4)·2C(3)H(7)NO, the central benzene and terminal hy­droxy­phenyl rings form a dihedral angle of 14.28 (11)° and the central C=C double bond adopts a trans configuration. In the crystal, the bis­chalcone and solvate mol­ecules are inter...

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Autores principales: Kwong, Huey Chong, Sim, Ai Jia, Chidan Kumar, C. S., Quah, Ching Kheng, Chantrapromma, Suchada, Naveen, S., Warad, Ismail
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002815/
https://www.ncbi.nlm.nih.gov/pubmed/29951241
http://dx.doi.org/10.1107/S2056989018007429
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author Kwong, Huey Chong
Sim, Ai Jia
Chidan Kumar, C. S.
Quah, Ching Kheng
Chantrapromma, Suchada
Naveen, S.
Warad, Ismail
author_facet Kwong, Huey Chong
Sim, Ai Jia
Chidan Kumar, C. S.
Quah, Ching Kheng
Chantrapromma, Suchada
Naveen, S.
Warad, Ismail
author_sort Kwong, Huey Chong
collection PubMed
description In the bis­chalcone mol­ecule of the title compound, C(24)H(18)O(4)·2C(3)H(7)NO, the central benzene and terminal hy­droxy­phenyl rings form a dihedral angle of 14.28 (11)° and the central C=C double bond adopts a trans configuration. In the crystal, the bis­chalcone and solvate mol­ecules are inter­connected via O—H⋯O hydrogen bonds, which were investigated by Hirshfeld surface analysis. Solid-state fluorescence was measured at λ(ex) = 4400 Å. The emission wavelength appeared at 5510 Å, which corresponds to yellow light and the solid-state fluorescence quantum yield (F (f)) is 0.18.
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spelling pubmed-60028152018-06-27 Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(4-hy­droxy­phen­yl)prop-2-en-1-one] N,N-di­methyl­formamide disolvate Kwong, Huey Chong Sim, Ai Jia Chidan Kumar, C. S. Quah, Ching Kheng Chantrapromma, Suchada Naveen, S. Warad, Ismail Acta Crystallogr E Crystallogr Commun Research Communications In the bis­chalcone mol­ecule of the title compound, C(24)H(18)O(4)·2C(3)H(7)NO, the central benzene and terminal hy­droxy­phenyl rings form a dihedral angle of 14.28 (11)° and the central C=C double bond adopts a trans configuration. In the crystal, the bis­chalcone and solvate mol­ecules are inter­connected via O—H⋯O hydrogen bonds, which were investigated by Hirshfeld surface analysis. Solid-state fluorescence was measured at λ(ex) = 4400 Å. The emission wavelength appeared at 5510 Å, which corresponds to yellow light and the solid-state fluorescence quantum yield (F (f)) is 0.18. International Union of Crystallography 2018-05-22 /pmc/articles/PMC6002815/ /pubmed/29951241 http://dx.doi.org/10.1107/S2056989018007429 Text en © Kwong et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Kwong, Huey Chong
Sim, Ai Jia
Chidan Kumar, C. S.
Quah, Ching Kheng
Chantrapromma, Suchada
Naveen, S.
Warad, Ismail
Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(4-hy­droxy­phen­yl)prop-2-en-1-one] N,N-di­methyl­formamide disolvate
title Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(4-hy­droxy­phen­yl)prop-2-en-1-one] N,N-di­methyl­formamide disolvate
title_full Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(4-hy­droxy­phen­yl)prop-2-en-1-one] N,N-di­methyl­formamide disolvate
title_fullStr Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(4-hy­droxy­phen­yl)prop-2-en-1-one] N,N-di­methyl­formamide disolvate
title_full_unstemmed Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(4-hy­droxy­phen­yl)prop-2-en-1-one] N,N-di­methyl­formamide disolvate
title_short Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenyl­ene)bis­[1-(4-hy­droxy­phen­yl)prop-2-en-1-one] N,N-di­methyl­formamide disolvate
title_sort synthesis, spectroscopic and hirshfeld surface analysis and fluorescence studies of (2e,2′e)-3,3′-(1,4-phenyl­ene)bis­[1-(4-hy­droxy­phen­yl)prop-2-en-1-one] n,n-di­methyl­formamide disolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002815/
https://www.ncbi.nlm.nih.gov/pubmed/29951241
http://dx.doi.org/10.1107/S2056989018007429
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