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Crystal structure of 3-hydroxy-2-(4-hydroxy-3-methoxyphenylmethyl)-5,5-dimethylcyclohex-2-enone
In the title compound, C(16)H(20)O(4), a new starting compound for the synthesis of various heterocycles, the partially saturated six-membered ring adopts a sofa conformation. An intramolecular O—H⋯O hydrogen bond is observed in the guaiacol residue. In the crystal, molecules are assembled into a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002819/ https://www.ncbi.nlm.nih.gov/pubmed/29951232 http://dx.doi.org/10.1107/S2056989018006941 |
Sumario: | In the title compound, C(16)H(20)O(4), a new starting compound for the synthesis of various heterocycles, the partially saturated six-membered ring adopts a sofa conformation. An intramolecular O—H⋯O hydrogen bond is observed in the guaiacol residue. In the crystal, molecules are assembled into a sheet structure parallel to the ab plane via O—H⋯O hydrogen bonds. The hydrogen-bond pattern is described by an R (4) (4)(28) graph-set motif. The sheets are further linked by C—H⋯O hydrogen bonds into a three-dimensional network. |
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