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Crystal structure of 3-hy­droxy-2-(4-hy­droxy-3-meth­oxy­phenyl­methyl)-5,5-di­methyl­cyclo­hex-2-enone

In the title compound, C(16)H(20)O(4), a new starting compound for the synthesis of various heterocycles, the partially saturated six-membered ring adopts a sofa conformation. An intra­molecular O—H⋯O hydrogen bond is observed in the guaiacol residue. In the crystal, mol­ecules are assembled into a...

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Detalles Bibliográficos
Autores principales: Stikute, Agnese, Skestere, Karina, Mierina, Inese, Mishnev, Anatoly, Jure, Mara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002819/
https://www.ncbi.nlm.nih.gov/pubmed/29951232
http://dx.doi.org/10.1107/S2056989018006941
Descripción
Sumario:In the title compound, C(16)H(20)O(4), a new starting compound for the synthesis of various heterocycles, the partially saturated six-membered ring adopts a sofa conformation. An intra­molecular O—H⋯O hydrogen bond is observed in the guaiacol residue. In the crystal, mol­ecules are assembled into a sheet structure parallel to the ab plane via O—H⋯O hydrogen bonds. The hydrogen-bond pattern is described by an R (4) (4)(28) graph-set motif. The sheets are further linked by C—H⋯O hydrogen bonds into a three-dimensional network.