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Crystal structure of bis(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetraphenylporphyrinato-κ(4) N)iron(II) tetrahydrofuran monosolvate
The title complex, [Fe(C(44)H(28)N(4))(C(5)H(8)N(2))(2)]·C(4)H(8)O, possesses inversion symmetry with the iron(II) atom located on a center of symmetry. The metal atom is coordinated in a symmetric octahedral geometry by four pyrrole N atoms of the porphyrin ligand in the equatorial plane and two N...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002823/ https://www.ncbi.nlm.nih.gov/pubmed/29951227 http://dx.doi.org/10.1107/S2056989018006308 |
Sumario: | The title complex, [Fe(C(44)H(28)N(4))(C(5)H(8)N(2))(2)]·C(4)H(8)O, possesses inversion symmetry with the iron(II) atom located on a center of symmetry. The metal atom is coordinated in a symmetric octahedral geometry by four pyrrole N atoms of the porphyrin ligand in the equatorial plane and two N atoms of 1-ethylimidazole ligands in the axial sites; the complex crystallizes with a tetrahydrofuran solvent molecule. The average Fe—N(p) (N(p) is a porphyrin N atom) bond length is 1.995 (3) Å and the axial Fe—N(Im) (N(Im) is an imidazole N atom) bond length is 1.994 (2) Å. The two 1-ethylimidazole ligands are mutually parallel. The dihedral angle between the 1-ethylimidazole plane and the plane of the closest Fe—N(p) vector is 24.5°. In the crystal, the only significant intermolecular interactions present are C—H⋯π interactions. |
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