Cargando…
Crystal structure of bis(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetraphenylporphyrinato-κ(4) N)iron(II) tetrahydrofuran monosolvate
The title complex, [Fe(C(44)H(28)N(4))(C(5)H(8)N(2))(2)]·C(4)H(8)O, possesses inversion symmetry with the iron(II) atom located on a center of symmetry. The metal atom is coordinated in a symmetric octahedral geometry by four pyrrole N atoms of the porphyrin ligand in the equatorial plane and two N...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002823/ https://www.ncbi.nlm.nih.gov/pubmed/29951227 http://dx.doi.org/10.1107/S2056989018006308 |
_version_ | 1783332273725112320 |
---|---|
author | Ding, Wei Li, Jianfeng |
author_facet | Ding, Wei Li, Jianfeng |
author_sort | Ding, Wei |
collection | PubMed |
description | The title complex, [Fe(C(44)H(28)N(4))(C(5)H(8)N(2))(2)]·C(4)H(8)O, possesses inversion symmetry with the iron(II) atom located on a center of symmetry. The metal atom is coordinated in a symmetric octahedral geometry by four pyrrole N atoms of the porphyrin ligand in the equatorial plane and two N atoms of 1-ethylimidazole ligands in the axial sites; the complex crystallizes with a tetrahydrofuran solvent molecule. The average Fe—N(p) (N(p) is a porphyrin N atom) bond length is 1.995 (3) Å and the axial Fe—N(Im) (N(Im) is an imidazole N atom) bond length is 1.994 (2) Å. The two 1-ethylimidazole ligands are mutually parallel. The dihedral angle between the 1-ethylimidazole plane and the plane of the closest Fe—N(p) vector is 24.5°. In the crystal, the only significant intermolecular interactions present are C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-6002823 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-60028232018-06-27 Crystal structure of bis(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetraphenylporphyrinato-κ(4) N)iron(II) tetrahydrofuran monosolvate Ding, Wei Li, Jianfeng Acta Crystallogr E Crystallogr Commun Research Communications The title complex, [Fe(C(44)H(28)N(4))(C(5)H(8)N(2))(2)]·C(4)H(8)O, possesses inversion symmetry with the iron(II) atom located on a center of symmetry. The metal atom is coordinated in a symmetric octahedral geometry by four pyrrole N atoms of the porphyrin ligand in the equatorial plane and two N atoms of 1-ethylimidazole ligands in the axial sites; the complex crystallizes with a tetrahydrofuran solvent molecule. The average Fe—N(p) (N(p) is a porphyrin N atom) bond length is 1.995 (3) Å and the axial Fe—N(Im) (N(Im) is an imidazole N atom) bond length is 1.994 (2) Å. The two 1-ethylimidazole ligands are mutually parallel. The dihedral angle between the 1-ethylimidazole plane and the plane of the closest Fe—N(p) vector is 24.5°. In the crystal, the only significant intermolecular interactions present are C—H⋯π interactions. International Union of Crystallography 2018-05-01 /pmc/articles/PMC6002823/ /pubmed/29951227 http://dx.doi.org/10.1107/S2056989018006308 Text en © Ding and Li 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Ding, Wei Li, Jianfeng Crystal structure of bis(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetraphenylporphyrinato-κ(4) N)iron(II) tetrahydrofuran monosolvate |
title | Crystal structure of bis(1-ethyl-1H-imidazole-κN
(3))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)iron(II) tetrahydrofuran monosolvate |
title_full | Crystal structure of bis(1-ethyl-1H-imidazole-κN
(3))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)iron(II) tetrahydrofuran monosolvate |
title_fullStr | Crystal structure of bis(1-ethyl-1H-imidazole-κN
(3))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)iron(II) tetrahydrofuran monosolvate |
title_full_unstemmed | Crystal structure of bis(1-ethyl-1H-imidazole-κN
(3))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)iron(II) tetrahydrofuran monosolvate |
title_short | Crystal structure of bis(1-ethyl-1H-imidazole-κN
(3))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)iron(II) tetrahydrofuran monosolvate |
title_sort | crystal structure of bis(1-ethyl-1h-imidazole-κn
(3))(5,10,15,20-tetraphenylporphyrinato-κ(4)
n)iron(ii) tetrahydrofuran monosolvate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002823/ https://www.ncbi.nlm.nih.gov/pubmed/29951227 http://dx.doi.org/10.1107/S2056989018006308 |
work_keys_str_mv | AT dingwei crystalstructureofbis1ethyl1himidazolekn35101520tetraphenylporphyrinatok4nironiitetrahydrofuranmonosolvate AT lijianfeng crystalstructureofbis1ethyl1himidazolekn35101520tetraphenylporphyrinatok4nironiitetrahydrofuranmonosolvate |