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Crystal structure of bis­(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) tetra­hydro­furan monosolvate

The title complex, [Fe(C(44)H(28)N(4))(C(5)H(8)N(2))(2)]·C(4)H(8)O, possesses inversion symmetry with the iron(II) atom located on a center of symmetry. The metal atom is coordinated in a symmetric octa­hedral geometry by four pyrrole N atoms of the porphyrin ligand in the equatorial plane and two N...

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Autores principales: Ding, Wei, Li, Jianfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002823/
https://www.ncbi.nlm.nih.gov/pubmed/29951227
http://dx.doi.org/10.1107/S2056989018006308
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author Ding, Wei
Li, Jianfeng
author_facet Ding, Wei
Li, Jianfeng
author_sort Ding, Wei
collection PubMed
description The title complex, [Fe(C(44)H(28)N(4))(C(5)H(8)N(2))(2)]·C(4)H(8)O, possesses inversion symmetry with the iron(II) atom located on a center of symmetry. The metal atom is coordinated in a symmetric octa­hedral geometry by four pyrrole N atoms of the porphyrin ligand in the equatorial plane and two N atoms of 1-ethyl­imidazole ligands in the axial sites; the complex crystallizes with a tetra­hydro­furan solvent mol­ecule. The average Fe—N(p) (N(p) is a porphyrin N atom) bond length is 1.995 (3) Å and the axial Fe—N(Im) (N(Im) is an imidazole N atom) bond length is 1.994 (2) Å. The two 1-ethyl­imidazole ligands are mutually parallel. The dihedral angle between the 1-ethyl­imidazole plane and the plane of the closest Fe—N(p) vector is 24.5°. In the crystal, the only significant inter­molecular inter­actions present are C—H⋯π inter­actions.
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spelling pubmed-60028232018-06-27 Crystal structure of bis­(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) tetra­hydro­furan monosolvate Ding, Wei Li, Jianfeng Acta Crystallogr E Crystallogr Commun Research Communications The title complex, [Fe(C(44)H(28)N(4))(C(5)H(8)N(2))(2)]·C(4)H(8)O, possesses inversion symmetry with the iron(II) atom located on a center of symmetry. The metal atom is coordinated in a symmetric octa­hedral geometry by four pyrrole N atoms of the porphyrin ligand in the equatorial plane and two N atoms of 1-ethyl­imidazole ligands in the axial sites; the complex crystallizes with a tetra­hydro­furan solvent mol­ecule. The average Fe—N(p) (N(p) is a porphyrin N atom) bond length is 1.995 (3) Å and the axial Fe—N(Im) (N(Im) is an imidazole N atom) bond length is 1.994 (2) Å. The two 1-ethyl­imidazole ligands are mutually parallel. The dihedral angle between the 1-ethyl­imidazole plane and the plane of the closest Fe—N(p) vector is 24.5°. In the crystal, the only significant inter­molecular inter­actions present are C—H⋯π inter­actions. International Union of Crystallography 2018-05-01 /pmc/articles/PMC6002823/ /pubmed/29951227 http://dx.doi.org/10.1107/S2056989018006308 Text en © Ding and Li 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Ding, Wei
Li, Jianfeng
Crystal structure of bis­(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) tetra­hydro­furan monosolvate
title Crystal structure of bis­(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) tetra­hydro­furan monosolvate
title_full Crystal structure of bis­(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) tetra­hydro­furan monosolvate
title_fullStr Crystal structure of bis­(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) tetra­hydro­furan monosolvate
title_full_unstemmed Crystal structure of bis­(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) tetra­hydro­furan monosolvate
title_short Crystal structure of bis­(1-ethyl-1H-imidazole-κN (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) tetra­hydro­furan monosolvate
title_sort crystal structure of bis­(1-ethyl-1h-imidazole-κn (3))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n)iron(ii) tetra­hydro­furan monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002823/
https://www.ncbi.nlm.nih.gov/pubmed/29951227
http://dx.doi.org/10.1107/S2056989018006308
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