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Crystal structure of (μ-trans-1,2-bis­{2-[(2-oxido­phen­yl)methyl­idene]hydrazin-1-yl­idene}ethane-1,2-diolato-κ(3) O,O′,N)bis­[di-tert-butyl­tin(IV)]

The binuclear complex, [Sn(2)(C(4)H(9))(4)(C(16)H(10)N(4)O(4))], contains two Sn(4+) ions, connected by doubly N-deprotonated oxalylbis[(2-oxido­benzyl­idene)hydrazide] ligands, and each Sn(4+) ion is linked to two tert-butyl groups. The coordination sphere of each Sn atom is best described as a dis...

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Autores principales: Ndoye, Cheikh, Diallo, Waly, Diouf, Ousmane, Barry, Aliou Hamady, Gaye, Mohamed, Gautier, Romain
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002830/
https://www.ncbi.nlm.nih.gov/pubmed/29951233
http://dx.doi.org/10.1107/S2056989018007077
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author Ndoye, Cheikh
Diallo, Waly
Diouf, Ousmane
Barry, Aliou Hamady
Gaye, Mohamed
Gautier, Romain
author_facet Ndoye, Cheikh
Diallo, Waly
Diouf, Ousmane
Barry, Aliou Hamady
Gaye, Mohamed
Gautier, Romain
author_sort Ndoye, Cheikh
collection PubMed
description The binuclear complex, [Sn(2)(C(4)H(9))(4)(C(16)H(10)N(4)O(4))], contains two Sn(4+) ions, connected by doubly N-deprotonated oxalylbis[(2-oxido­benzyl­idene)hydrazide] ligands, and each Sn(4+) ion is linked to two tert-butyl groups. The coordination sphere of each Sn atom is best described as a distorted trigonal bipyramid. Each stannic ion in the complex is in a C(2)O(2)N environment. The two homologous parts of the doubly deprotonated ligand are located in trans positions with respect to the C—C bond of the oxalamide group. The oxalamide group exhibits an asymmetric coordination geometry, as seen by the slight difference between the C—O and C—N bond lengths. The three-dimensional network is a multilayer of complex mol­ecules with no strong supramolecular inter­actions.
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spelling pubmed-60028302018-06-27 Crystal structure of (μ-trans-1,2-bis­{2-[(2-oxido­phen­yl)methyl­idene]hydrazin-1-yl­idene}ethane-1,2-diolato-κ(3) O,O′,N)bis­[di-tert-butyl­tin(IV)] Ndoye, Cheikh Diallo, Waly Diouf, Ousmane Barry, Aliou Hamady Gaye, Mohamed Gautier, Romain Acta Crystallogr E Crystallogr Commun Research Communications The binuclear complex, [Sn(2)(C(4)H(9))(4)(C(16)H(10)N(4)O(4))], contains two Sn(4+) ions, connected by doubly N-deprotonated oxalylbis[(2-oxido­benzyl­idene)hydrazide] ligands, and each Sn(4+) ion is linked to two tert-butyl groups. The coordination sphere of each Sn atom is best described as a distorted trigonal bipyramid. Each stannic ion in the complex is in a C(2)O(2)N environment. The two homologous parts of the doubly deprotonated ligand are located in trans positions with respect to the C—C bond of the oxalamide group. The oxalamide group exhibits an asymmetric coordination geometry, as seen by the slight difference between the C—O and C—N bond lengths. The three-dimensional network is a multilayer of complex mol­ecules with no strong supramolecular inter­actions. International Union of Crystallography 2018-05-15 /pmc/articles/PMC6002830/ /pubmed/29951233 http://dx.doi.org/10.1107/S2056989018007077 Text en © Ndoye et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Ndoye, Cheikh
Diallo, Waly
Diouf, Ousmane
Barry, Aliou Hamady
Gaye, Mohamed
Gautier, Romain
Crystal structure of (μ-trans-1,2-bis­{2-[(2-oxido­phen­yl)methyl­idene]hydrazin-1-yl­idene}ethane-1,2-diolato-κ(3) O,O′,N)bis­[di-tert-butyl­tin(IV)]
title Crystal structure of (μ-trans-1,2-bis­{2-[(2-oxido­phen­yl)methyl­idene]hydrazin-1-yl­idene}ethane-1,2-diolato-κ(3) O,O′,N)bis­[di-tert-butyl­tin(IV)]
title_full Crystal structure of (μ-trans-1,2-bis­{2-[(2-oxido­phen­yl)methyl­idene]hydrazin-1-yl­idene}ethane-1,2-diolato-κ(3) O,O′,N)bis­[di-tert-butyl­tin(IV)]
title_fullStr Crystal structure of (μ-trans-1,2-bis­{2-[(2-oxido­phen­yl)methyl­idene]hydrazin-1-yl­idene}ethane-1,2-diolato-κ(3) O,O′,N)bis­[di-tert-butyl­tin(IV)]
title_full_unstemmed Crystal structure of (μ-trans-1,2-bis­{2-[(2-oxido­phen­yl)methyl­idene]hydrazin-1-yl­idene}ethane-1,2-diolato-κ(3) O,O′,N)bis­[di-tert-butyl­tin(IV)]
title_short Crystal structure of (μ-trans-1,2-bis­{2-[(2-oxido­phen­yl)methyl­idene]hydrazin-1-yl­idene}ethane-1,2-diolato-κ(3) O,O′,N)bis­[di-tert-butyl­tin(IV)]
title_sort crystal structure of (μ-trans-1,2-bis­{2-[(2-oxido­phen­yl)methyl­idene]hydrazin-1-yl­idene}ethane-1,2-diolato-κ(3) o,o′,n)bis­[di-tert-butyl­tin(iv)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002830/
https://www.ncbi.nlm.nih.gov/pubmed/29951233
http://dx.doi.org/10.1107/S2056989018007077
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