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Crystal structure of (μ-trans-1,2-bis{2-[(2-oxidophenyl)methylidene]hydrazin-1-ylidene}ethane-1,2-diolato-κ(3) O,O′,N)bis[di-tert-butyltin(IV)]
The binuclear complex, [Sn(2)(C(4)H(9))(4)(C(16)H(10)N(4)O(4))], contains two Sn(4+) ions, connected by doubly N-deprotonated oxalylbis[(2-oxidobenzylidene)hydrazide] ligands, and each Sn(4+) ion is linked to two tert-butyl groups. The coordination sphere of each Sn atom is best described as a dis...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002830/ https://www.ncbi.nlm.nih.gov/pubmed/29951233 http://dx.doi.org/10.1107/S2056989018007077 |
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author | Ndoye, Cheikh Diallo, Waly Diouf, Ousmane Barry, Aliou Hamady Gaye, Mohamed Gautier, Romain |
author_facet | Ndoye, Cheikh Diallo, Waly Diouf, Ousmane Barry, Aliou Hamady Gaye, Mohamed Gautier, Romain |
author_sort | Ndoye, Cheikh |
collection | PubMed |
description | The binuclear complex, [Sn(2)(C(4)H(9))(4)(C(16)H(10)N(4)O(4))], contains two Sn(4+) ions, connected by doubly N-deprotonated oxalylbis[(2-oxidobenzylidene)hydrazide] ligands, and each Sn(4+) ion is linked to two tert-butyl groups. The coordination sphere of each Sn atom is best described as a distorted trigonal bipyramid. Each stannic ion in the complex is in a C(2)O(2)N environment. The two homologous parts of the doubly deprotonated ligand are located in trans positions with respect to the C—C bond of the oxalamide group. The oxalamide group exhibits an asymmetric coordination geometry, as seen by the slight difference between the C—O and C—N bond lengths. The three-dimensional network is a multilayer of complex molecules with no strong supramolecular interactions. |
format | Online Article Text |
id | pubmed-6002830 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-60028302018-06-27 Crystal structure of (μ-trans-1,2-bis{2-[(2-oxidophenyl)methylidene]hydrazin-1-ylidene}ethane-1,2-diolato-κ(3) O,O′,N)bis[di-tert-butyltin(IV)] Ndoye, Cheikh Diallo, Waly Diouf, Ousmane Barry, Aliou Hamady Gaye, Mohamed Gautier, Romain Acta Crystallogr E Crystallogr Commun Research Communications The binuclear complex, [Sn(2)(C(4)H(9))(4)(C(16)H(10)N(4)O(4))], contains two Sn(4+) ions, connected by doubly N-deprotonated oxalylbis[(2-oxidobenzylidene)hydrazide] ligands, and each Sn(4+) ion is linked to two tert-butyl groups. The coordination sphere of each Sn atom is best described as a distorted trigonal bipyramid. Each stannic ion in the complex is in a C(2)O(2)N environment. The two homologous parts of the doubly deprotonated ligand are located in trans positions with respect to the C—C bond of the oxalamide group. The oxalamide group exhibits an asymmetric coordination geometry, as seen by the slight difference between the C—O and C—N bond lengths. The three-dimensional network is a multilayer of complex molecules with no strong supramolecular interactions. International Union of Crystallography 2018-05-15 /pmc/articles/PMC6002830/ /pubmed/29951233 http://dx.doi.org/10.1107/S2056989018007077 Text en © Ndoye et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Ndoye, Cheikh Diallo, Waly Diouf, Ousmane Barry, Aliou Hamady Gaye, Mohamed Gautier, Romain Crystal structure of (μ-trans-1,2-bis{2-[(2-oxidophenyl)methylidene]hydrazin-1-ylidene}ethane-1,2-diolato-κ(3) O,O′,N)bis[di-tert-butyltin(IV)] |
title | Crystal structure of (μ-trans-1,2-bis{2-[(2-oxidophenyl)methylidene]hydrazin-1-ylidene}ethane-1,2-diolato-κ(3)
O,O′,N)bis[di-tert-butyltin(IV)] |
title_full | Crystal structure of (μ-trans-1,2-bis{2-[(2-oxidophenyl)methylidene]hydrazin-1-ylidene}ethane-1,2-diolato-κ(3)
O,O′,N)bis[di-tert-butyltin(IV)] |
title_fullStr | Crystal structure of (μ-trans-1,2-bis{2-[(2-oxidophenyl)methylidene]hydrazin-1-ylidene}ethane-1,2-diolato-κ(3)
O,O′,N)bis[di-tert-butyltin(IV)] |
title_full_unstemmed | Crystal structure of (μ-trans-1,2-bis{2-[(2-oxidophenyl)methylidene]hydrazin-1-ylidene}ethane-1,2-diolato-κ(3)
O,O′,N)bis[di-tert-butyltin(IV)] |
title_short | Crystal structure of (μ-trans-1,2-bis{2-[(2-oxidophenyl)methylidene]hydrazin-1-ylidene}ethane-1,2-diolato-κ(3)
O,O′,N)bis[di-tert-butyltin(IV)] |
title_sort | crystal structure of (μ-trans-1,2-bis{2-[(2-oxidophenyl)methylidene]hydrazin-1-ylidene}ethane-1,2-diolato-κ(3)
o,o′,n)bis[di-tert-butyltin(iv)] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002830/ https://www.ncbi.nlm.nih.gov/pubmed/29951233 http://dx.doi.org/10.1107/S2056989018007077 |
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