Crystal structure of 1-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]-2-bromo­ethan-1-one

The title compound, C(10)H(5)BrF(6)O, synthesized via continuous stirring of 3,5-bis­(tri­fluoro­meth­yl) aceto­phenone with bromine in an acidic medium and concentrated under reduced pressure, crystallizes with four mol­ecules in the unit cell (Z = 4) and one formula unit in the asymmetric unit. In...

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Autores principales: Chandrashekharappa, Sandeep, Bairagi, Keshab M., Mohan, Mahendra K., Mohanlall, Viresh, Kasumbwe, Kabange, Venugopala, Katharigatta N., Nayak, Susanta K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002836/
https://www.ncbi.nlm.nih.gov/pubmed/29951247
http://dx.doi.org/10.1107/S2056989018007478
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author Chandrashekharappa, Sandeep
Bairagi, Keshab M.
Mohan, Mahendra K.
Mohanlall, Viresh
Kasumbwe, Kabange
Venugopala, Katharigatta N.
Nayak, Susanta K.
author_facet Chandrashekharappa, Sandeep
Bairagi, Keshab M.
Mohan, Mahendra K.
Mohanlall, Viresh
Kasumbwe, Kabange
Venugopala, Katharigatta N.
Nayak, Susanta K.
author_sort Chandrashekharappa, Sandeep
collection PubMed
description The title compound, C(10)H(5)BrF(6)O, synthesized via continuous stirring of 3,5-bis­(tri­fluoro­meth­yl) aceto­phenone with bromine in an acidic medium and concentrated under reduced pressure, crystallizes with four mol­ecules in the unit cell (Z = 4) and one formula unit in the asymmetric unit. In the crystal, mol­ecules are linked in a head-to-tail fashion into dimers along the b-axis direction through weak C—H⋯Br and C—O⋯Csp (2) inter­actions. C—H⋯O, C—F⋯π and F⋯F inter­actions are also observed.
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spelling pubmed-60028362018-06-27 Crystal structure of 1-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]-2-bromo­ethan-1-one Chandrashekharappa, Sandeep Bairagi, Keshab M. Mohan, Mahendra K. Mohanlall, Viresh Kasumbwe, Kabange Venugopala, Katharigatta N. Nayak, Susanta K. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(10)H(5)BrF(6)O, synthesized via continuous stirring of 3,5-bis­(tri­fluoro­meth­yl) aceto­phenone with bromine in an acidic medium and concentrated under reduced pressure, crystallizes with four mol­ecules in the unit cell (Z = 4) and one formula unit in the asymmetric unit. In the crystal, mol­ecules are linked in a head-to-tail fashion into dimers along the b-axis direction through weak C—H⋯Br and C—O⋯Csp (2) inter­actions. C—H⋯O, C—F⋯π and F⋯F inter­actions are also observed. International Union of Crystallography 2018-05-31 /pmc/articles/PMC6002836/ /pubmed/29951247 http://dx.doi.org/10.1107/S2056989018007478 Text en © Chandrashekharappa et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Chandrashekharappa, Sandeep
Bairagi, Keshab M.
Mohan, Mahendra K.
Mohanlall, Viresh
Kasumbwe, Kabange
Venugopala, Katharigatta N.
Nayak, Susanta K.
Crystal structure of 1-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]-2-bromo­ethan-1-one
title Crystal structure of 1-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]-2-bromo­ethan-1-one
title_full Crystal structure of 1-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]-2-bromo­ethan-1-one
title_fullStr Crystal structure of 1-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]-2-bromo­ethan-1-one
title_full_unstemmed Crystal structure of 1-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]-2-bromo­ethan-1-one
title_short Crystal structure of 1-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]-2-bromo­ethan-1-one
title_sort crystal structure of 1-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]-2-bromo­ethan-1-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6002836/
https://www.ncbi.nlm.nih.gov/pubmed/29951247
http://dx.doi.org/10.1107/S2056989018007478
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