Strong Brønsted acid promoted asymmetric hydrogenation of isoquinolines and quinolines catalyzed by a Rh–thiourea chiral phosphine complex via anion binding

Rhodium catalyzed asymmetric hydrogenation of both isoquinolines and quinolines provides a new method to synthesize chiral tetrahydroisoquinolines and tetrahydroquinolines. By introducing strong Brønsted acid HCl, anion binding between the substrate and the ligand was established to achieve high rea...

Descripción completa

Detalles Bibliográficos
Autores principales: Wen, Jialin, Tan, Renchang, Liu, Shaodong, Zhao, Qingyang, Zhang, Xumu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6005156/
https://www.ncbi.nlm.nih.gov/pubmed/29997795
http://dx.doi.org/10.1039/c5sc04712a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6005156/
https://www.ncbi.nlm.nih.gov/pubmed/29997795
http://dx.doi.org/10.1039/c5sc04712a

Ejemplares similares