Iridium(iii)-bis(imidazolinyl)phenyl catalysts for enantioselective C–H functionalization with ethyl diazoacetate

The intermolecular enantioselective C–H functionalization with acceptor-only metallocarbenes is reported using a new family of Ir(iii)-bis(imidazolinyl)phenyl catalysts, developed based on the interplay of experimental and computational insights. The reaction is tolerant of a variety of diazoacetate...

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Detalles Bibliográficos
Autores principales: Weldy, N. Mace, Schafer, A. G., Owens, C. P., Herting, C. J., Varela-Alvarez, A., Chen, S., Niemeyer, Z., Musaev, D. G., Sigman, M. S., Davies, H. M. L., Blakey, S. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6005272/
https://www.ncbi.nlm.nih.gov/pubmed/29997805
http://dx.doi.org/10.1039/c6sc00190d

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