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Dynamic helical cyclophanes with two quadruply-bridged planes arranged in an “obverse and/or reverse” relation

We describe the design of two types of cyclophanes that generate dynamic helicity through the twisting of two planes in a clockwise or counterclockwise direction to give (M)- or (P)-helicity. We used a rectangular and anisotropic plane of 1,2,4,5-tetrakis(phenylethynyl)benzene (TPEB), since it can b...

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Detalles Bibliográficos
Autores principales: Katoono, Ryo, Kawai, Shunsuke, Suzuki, Takanori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6006470/
https://www.ncbi.nlm.nih.gov/pubmed/29997816
http://dx.doi.org/10.1039/c5sc04673d