Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols

A highly efficient, gold-catalyzed intramolecular dearomatization reaction of naphthols via 5-endo-dig cyclization is described. This facile and direct approach furnishes spirocarbocycles in excellent yields under mild conditions.

Detalles Bibliográficos
Autores principales: Wu, Wen-Ting, Xu, Ren-Qi, Zhang, Liming, You, Shu-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6006865/
https://www.ncbi.nlm.nih.gov/pubmed/29997837
http://dx.doi.org/10.1039/c5sc04130a
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author Wu, Wen-Ting
Xu, Ren-Qi
Zhang, Liming
You, Shu-Li
author_facet Wu, Wen-Ting
Xu, Ren-Qi
Zhang, Liming
You, Shu-Li
author_sort Wu, Wen-Ting
collection PubMed
description A highly efficient, gold-catalyzed intramolecular dearomatization reaction of naphthols via 5-endo-dig cyclization is described. This facile and direct approach furnishes spirocarbocycles in excellent yields under mild conditions.
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spelling pubmed-60068652018-07-11 Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols Wu, Wen-Ting Xu, Ren-Qi Zhang, Liming You, Shu-Li Chem Sci Chemistry A highly efficient, gold-catalyzed intramolecular dearomatization reaction of naphthols via 5-endo-dig cyclization is described. This facile and direct approach furnishes spirocarbocycles in excellent yields under mild conditions. Royal Society of Chemistry 2016-05-01 2016-02-02 /pmc/articles/PMC6006865/ /pubmed/29997837 http://dx.doi.org/10.1039/c5sc04130a Text en This journal is © The Royal Society of Chemistry 2016 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Wu, Wen-Ting
Xu, Ren-Qi
Zhang, Liming
You, Shu-Li
Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols
title Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols
title_full Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols
title_fullStr Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols
title_full_unstemmed Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols
title_short Construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols
title_sort construction of spirocarbocycles via gold-catalyzed intramolecular dearomatization of naphthols
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6006865/
https://www.ncbi.nlm.nih.gov/pubmed/29997837
http://dx.doi.org/10.1039/c5sc04130a
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AT zhangliming constructionofspirocarbocyclesviagoldcatalyzedintramoleculardearomatizationofnaphthols
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