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Comment on “A quantitative definition of hypervalency” by M. C. Durrant, Chem. Sci., 2015, 6, 6614
Consideration is given to (electronically) hypervalent increased-valence structures, which possess 2c–1e bonds, fractional 2c–2e bonds, and usually normal 2c–2e bonds. For singlet-spin electron-rich systems, increased-valence structures, with Heitler–London 2c–2e bond wavefunctions, are equivalent t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6007126/ https://www.ncbi.nlm.nih.gov/pubmed/29999045 http://dx.doi.org/10.1039/c5sc04866d |