The Raman fingerprint of cyclic conjugation: the case of the stabilization of cations and dications in cycloparaphenylenes

Radical cations and dications of [n]CPP from n = 5 to n = 12 have been studied by Raman spectroscopy and density functional theory. Small [n]CPP dications owe their stability to the closed-shell electronic structure imposed by cyclic conjugation surpassing the destabilizing effect of ring strain and...

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Detalles Bibliográficos
Autores principales: Alvarez, Miriam Peña, Ruiz Delgado, M. Carmen, Taravillo, Mercedes, Baonza, Valentín G., López Navarrete, Juan T., Evans, Paul, Jasti, Ramesh, Yamago, Shigeru, Kertesz, Miklos, Casado, Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6007183/
https://www.ncbi.nlm.nih.gov/pubmed/29997841
http://dx.doi.org/10.1039/c6sc00765a

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