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“Inverse” thermoresponse: heat-induced double-helix formation of an ethynylhelicene oligomer with tri(ethylene glycol) termini
An ethynylhelicene oligomer [(M)-d-4]-C(12)-TEG with six tri(ethylene glycol) (TEG) groups at the termini was synthesized, and double-helix formation was studied using CD, UV-Vis, vapor pressure osmometry, dynamic light scattering, and (1)H NMR. [(M)-d-4]-C(12)-TEG reversibly changed its structure b...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6007355/ https://www.ncbi.nlm.nih.gov/pubmed/29997850 http://dx.doi.org/10.1039/c5sc04959h |