Cyanide-bridged iron complexes as biomimetics of tri-iron arrangements in maturases of the H cluster of the di-iron hydrogenase

Developing from certain catalytic processes required for ancient life forms, the H(2) processing enzymes [NiFe]- and [FeFe]-hydrogenase (H(2)ase) have active sites that are organometallic in composition, possessing carbon monoxide and cyanide as ligands. Simple synthetic analogues of the 2Fe portion...

Descripción completa

Detalles Bibliográficos
Autores principales: Lunsford, Allen M., Beto, Christopher C., Ding, Shengda, Erdem, Özlen F., Wang, Ning, Bhuvanesh, Nattamai, Hall, Michael B., Darensbourg, Marcetta Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6008931/
https://www.ncbi.nlm.nih.gov/pubmed/30009000
http://dx.doi.org/10.1039/c6sc00213g

Ejemplares similares

Ejemplares similares