A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds

The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and...

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Detalles Bibliográficos
Autores principales: Lar, Claudia, Woiczechowski-Pop, Adrian, Bende, Attila, Grosu, Ioana Georgeta, Miklášová, Natalia, Bogdan, Elena, Hădade, Niculina Daniela, Terec, Anamaria, Grosu, Ion
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009098/
https://www.ncbi.nlm.nih.gov/pubmed/29977401
http://dx.doi.org/10.3762/bjoc.14.115
Descripción
Sumario:The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and molecular modelling investigations proved the formation of 1:1 host–guest assemblies between the investigated cryptand and some polynuclear aromatic hydrocarbons or their derivatives.

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