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A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds
The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009098/ https://www.ncbi.nlm.nih.gov/pubmed/29977401 http://dx.doi.org/10.3762/bjoc.14.115 |
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author | Lar, Claudia Woiczechowski-Pop, Adrian Bende, Attila Grosu, Ioana Georgeta Miklášová, Natalia Bogdan, Elena Hădade, Niculina Daniela Terec, Anamaria Grosu, Ion |
author_facet | Lar, Claudia Woiczechowski-Pop, Adrian Bende, Attila Grosu, Ioana Georgeta Miklášová, Natalia Bogdan, Elena Hădade, Niculina Daniela Terec, Anamaria Grosu, Ion |
author_sort | Lar, Claudia |
collection | PubMed |
description | The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and molecular modelling investigations proved the formation of 1:1 host–guest assemblies between the investigated cryptand and some polynuclear aromatic hydrocarbons or their derivatives. |
format | Online Article Text |
id | pubmed-6009098 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-60090982018-07-05 A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds Lar, Claudia Woiczechowski-Pop, Adrian Bende, Attila Grosu, Ioana Georgeta Miklášová, Natalia Bogdan, Elena Hădade, Niculina Daniela Terec, Anamaria Grosu, Ion Beilstein J Org Chem Full Research Paper The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and molecular modelling investigations proved the formation of 1:1 host–guest assemblies between the investigated cryptand and some polynuclear aromatic hydrocarbons or their derivatives. Beilstein-Institut 2018-06-06 /pmc/articles/PMC6009098/ /pubmed/29977401 http://dx.doi.org/10.3762/bjoc.14.115 Text en Copyright © 2018, Lar et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
spellingShingle | Full Research Paper Lar, Claudia Woiczechowski-Pop, Adrian Bende, Attila Grosu, Ioana Georgeta Miklášová, Natalia Bogdan, Elena Hădade, Niculina Daniela Terec, Anamaria Grosu, Ion A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds |
title | A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds |
title_full | A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds |
title_fullStr | A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds |
title_full_unstemmed | A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds |
title_short | A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds |
title_sort | three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds |
topic | Full Research Paper |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009098/ https://www.ncbi.nlm.nih.gov/pubmed/29977401 http://dx.doi.org/10.3762/bjoc.14.115 |
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