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An N-heterocyclic carbene ligand promotes highly selective alkyne semihydrogenation with copper nanoparticles supported on passivated silica

We report a surface organometallic route that generates copper nanoparticles (NPs) on a silica support while simultaneously passivating the silica surface with trimethylsiloxy groups. The material is active for the catalytic semihydrogenation of phenylalkyl-, dialkyl- and diaryl-alkynes and displays...

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Detalles Bibliográficos
Autores principales:	Kaeffer, Nicolas, Liu, Hsueh-Ju, Lo, Hung-Kun, Fedorov, Alexey, Copéret, Christophe
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009536/ https://www.ncbi.nlm.nih.gov/pubmed/30009008 http://dx.doi.org/10.1039/c8sc01924j

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