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Fluorocyclisation via I(I)/I(III) catalysis: a concise route to fluorinated oxazolines

Herein, we describe a catalytic fluorooxygenation of readily accessible N-allylcarboxamides via an I(I)/I(III) manifold to generate 2-oxazolines containing a fluoromethyl group. Catalysis is conditional on the oxidation competence of Selectfluor(®), whilst HF serves as both a fluoride source and Brø...

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Detalles Bibliográficos
Autores principales: Scheidt, Felix, Thiehoff, Christian, Yilmaz, Gülay, Meyer, Stephanie, Daniliuc, Constantin G, Kehr, Gerald, Gilmour, Ryan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6009682/
https://www.ncbi.nlm.nih.gov/pubmed/29977374
http://dx.doi.org/10.3762/bjoc.14.88