Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In(2)O(3−) (x)(OH)(y) for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO(2) by Isomorphous Substitution of In(3+) with Bi(3+) (Adv. Sci. 6/2018)

The excited state acidity and basicity of surface frustrated Lewis pairs in oxygen vacancy and hydroxide defect laden Bi(z)In(2−z)O(3−x)OH(y) can be chemically tailored by controlling the level of isomorphous substitution of Bi(III) for In(III). As shown in article number https://doi.org/10.1002/adv...

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Detalles Bibliográficos
Autores principales: Dong, Yuchan, Ghuman, Kulbir Kaur, Popescu, Radian, Duchesne, Paul N., Zhou, Wenjie, Loh, Joel Y. Y., Jelle, Abdinoor A., Jia, Jia, Wang, Di, Mu, Xiaoke, Kübel, Christian, Wang, Lu, He, Le, Ghoussoub, Mireille, Wang, Qiang, Wood, Thomas E., Reyes, Laura M., Zhang, Peng, Kherani, Nazir P., Singh, Chandra Veer, Ozin, Geoffrey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Inside Front Cover
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6010710/
http://dx.doi.org/10.1002/advs.201870034
Descripción
Sumario:The excited state acidity and basicity of surface frustrated Lewis pairs in oxygen vacancy and hydroxide defect laden Bi(z)In(2−z)O(3−x)OH(y) can be chemically tailored by controlling the level of isomorphous substitution of Bi(III) for In(III). As shown in article number https://doi.org/10.1002/advs.201700732 by Chandra Veer Singh, Geoffrey A. Ozin, and co‐workers, this makes it possible to optimize the catalytic performance of the solar powered reverse water gas shift reaction. [Image: see text]

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