Cargando…

Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In(2)O(3−) (x)(OH)(y) for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO(2) by Isomorphous Substitution of In(3+) with Bi(3+) (Adv. Sci. 6/2018)

The excited state acidity and basicity of surface frustrated Lewis pairs in oxygen vacancy and hydroxide defect laden Bi(z)In(2−z)O(3−x)OH(y) can be chemically tailored by controlling the level of isomorphous substitution of Bi(III) for In(III). As shown in article number https://doi.org/10.1002/adv...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Yuchan, Ghuman, Kulbir Kaur, Popescu, Radian, Duchesne, Paul N., Zhou, Wenjie, Loh, Joel Y. Y., Jelle, Abdinoor A., Jia, Jia, Wang, Di, Mu, Xiaoke, Kübel, Christian, Wang, Lu, He, Le, Ghoussoub, Mireille, Wang, Qiang, Wood, Thomas E., Reyes, Laura M., Zhang, Peng, Kherani, Nazir P., Singh, Chandra Veer, Ozin, Geoffrey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6010710/
http://dx.doi.org/10.1002/advs.201870034
_version_ 1783333641301000192
author Dong, Yuchan
Ghuman, Kulbir Kaur
Popescu, Radian
Duchesne, Paul N.
Zhou, Wenjie
Loh, Joel Y. Y.
Jelle, Abdinoor A.
Jia, Jia
Wang, Di
Mu, Xiaoke
Kübel, Christian
Wang, Lu
He, Le
Ghoussoub, Mireille
Wang, Qiang
Wood, Thomas E.
Reyes, Laura M.
Zhang, Peng
Kherani, Nazir P.
Singh, Chandra Veer
Ozin, Geoffrey A.
author_facet Dong, Yuchan
Ghuman, Kulbir Kaur
Popescu, Radian
Duchesne, Paul N.
Zhou, Wenjie
Loh, Joel Y. Y.
Jelle, Abdinoor A.
Jia, Jia
Wang, Di
Mu, Xiaoke
Kübel, Christian
Wang, Lu
He, Le
Ghoussoub, Mireille
Wang, Qiang
Wood, Thomas E.
Reyes, Laura M.
Zhang, Peng
Kherani, Nazir P.
Singh, Chandra Veer
Ozin, Geoffrey A.
author_sort Dong, Yuchan
collection PubMed
description The excited state acidity and basicity of surface frustrated Lewis pairs in oxygen vacancy and hydroxide defect laden Bi(z)In(2−z)O(3−x)OH(y) can be chemically tailored by controlling the level of isomorphous substitution of Bi(III) for In(III). As shown in article number https://doi.org/10.1002/advs.201700732 by Chandra Veer Singh, Geoffrey A. Ozin, and co‐workers, this makes it possible to optimize the catalytic performance of the solar powered reverse water gas shift reaction. [Image: see text]
format Online
Article
Text
id pubmed-6010710
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-60107102018-06-22 Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In(2)O(3−) (x)(OH)(y) for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO(2) by Isomorphous Substitution of In(3+) with Bi(3+) (Adv. Sci. 6/2018) Dong, Yuchan Ghuman, Kulbir Kaur Popescu, Radian Duchesne, Paul N. Zhou, Wenjie Loh, Joel Y. Y. Jelle, Abdinoor A. Jia, Jia Wang, Di Mu, Xiaoke Kübel, Christian Wang, Lu He, Le Ghoussoub, Mireille Wang, Qiang Wood, Thomas E. Reyes, Laura M. Zhang, Peng Kherani, Nazir P. Singh, Chandra Veer Ozin, Geoffrey A. Adv Sci (Weinh) Inside Front Cover The excited state acidity and basicity of surface frustrated Lewis pairs in oxygen vacancy and hydroxide defect laden Bi(z)In(2−z)O(3−x)OH(y) can be chemically tailored by controlling the level of isomorphous substitution of Bi(III) for In(III). As shown in article number https://doi.org/10.1002/advs.201700732 by Chandra Veer Singh, Geoffrey A. Ozin, and co‐workers, this makes it possible to optimize the catalytic performance of the solar powered reverse water gas shift reaction. [Image: see text] John Wiley and Sons Inc. 2018-06-19 /pmc/articles/PMC6010710/ http://dx.doi.org/10.1002/advs.201870034 Text en © 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Inside Front Cover
Dong, Yuchan
Ghuman, Kulbir Kaur
Popescu, Radian
Duchesne, Paul N.
Zhou, Wenjie
Loh, Joel Y. Y.
Jelle, Abdinoor A.
Jia, Jia
Wang, Di
Mu, Xiaoke
Kübel, Christian
Wang, Lu
He, Le
Ghoussoub, Mireille
Wang, Qiang
Wood, Thomas E.
Reyes, Laura M.
Zhang, Peng
Kherani, Nazir P.
Singh, Chandra Veer
Ozin, Geoffrey A.
Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In(2)O(3−) (x)(OH)(y) for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO(2) by Isomorphous Substitution of In(3+) with Bi(3+) (Adv. Sci. 6/2018)
title Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In(2)O(3−) (x)(OH)(y) for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO(2) by Isomorphous Substitution of In(3+) with Bi(3+) (Adv. Sci. 6/2018)
title_full Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In(2)O(3−) (x)(OH)(y) for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO(2) by Isomorphous Substitution of In(3+) with Bi(3+) (Adv. Sci. 6/2018)
title_fullStr Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In(2)O(3−) (x)(OH)(y) for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO(2) by Isomorphous Substitution of In(3+) with Bi(3+) (Adv. Sci. 6/2018)
title_full_unstemmed Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In(2)O(3−) (x)(OH)(y) for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO(2) by Isomorphous Substitution of In(3+) with Bi(3+) (Adv. Sci. 6/2018)
title_short Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In(2)O(3−) (x)(OH)(y) for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO(2) by Isomorphous Substitution of In(3+) with Bi(3+) (Adv. Sci. 6/2018)
title_sort solar fuels: tailoring surface frustrated lewis pairs of in(2)o(3−) (x)(oh)(y) for gas‐phase heterogeneous photocatalytic reduction of co(2) by isomorphous substitution of in(3+) with bi(3+) (adv. sci. 6/2018)
topic Inside Front Cover
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6010710/
http://dx.doi.org/10.1002/advs.201870034
work_keys_str_mv AT dongyuchan solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT ghumankulbirkaur solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT popescuradian solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT duchesnepauln solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT zhouwenjie solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT lohjoelyy solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT jelleabdinoora solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT jiajia solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT wangdi solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT muxiaoke solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT kubelchristian solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT wanglu solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT hele solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT ghoussoubmireille solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT wangqiang solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT woodthomase solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT reyeslauram solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT zhangpeng solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT kheraninazirp solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT singhchandraveer solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018
AT ozingeoffreya solarfuelstailoringsurfacefrustratedlewispairsofin2o3xohyforgasphaseheterogeneousphotocatalyticreductionofco2byisomorphoussubstitutionofin3withbi3advsci62018