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Dynamic tungsten diselenide nanomaterials: supramolecular assembly-induced structural transition over exfoliated two-dimensional nanosheets
A simple and effective method for direct exfoliation of tungsten diselenide (WSe(2)) into few-layered nanosheets has been successfully developed by employing a low molecular weight adenine-functionalized supramolecular polymer (A-PPG). In this study, we discover A-PPG can self-assemble into a long-r...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6011224/ https://www.ncbi.nlm.nih.gov/pubmed/30155235 http://dx.doi.org/10.1039/c8sc01778f |
Sumario: | A simple and effective method for direct exfoliation of tungsten diselenide (WSe(2)) into few-layered nanosheets has been successfully developed by employing a low molecular weight adenine-functionalized supramolecular polymer (A-PPG). In this study, we discover A-PPG can self-assemble into a long-range, ordered lamellar microstructure on the surface of WSe(2) due to the efficient non-covalent interactions between A-PPG and WSe(2). Morphological and light scattering studies confirmed the dynamic self-assembly behavior of A-PPG has the capacity to efficiently manipulate the transition between contractile and extended lamellar microstructures on the surface of metallic 1T-phase and semiconducting 2H-phase WSe(2) nanosheets, respectively. The extent of WSe(2) exfoliation can be easily controlled by systematically adjusting the amount of A-PPG in the composites, to obtain nanocomposites with the desired functional characteristics. In addition, the resulting composites possess unique liquid–solid phase transition behavior and excellent thermoreversible properties, revealing the self-assembled lamellar structure of A-PPG functions as a critical factor to manipulate and tailor the physical properties of exfoliated WSe(2). This newly developed method of producing exfoliated WSe(2) provides a useful conceptual and potential framework for developing WSe(2)-based multifunctional nanocomposites to extend their application in solution-processed semiconductor devices. |
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