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Ring-opening copolymerization thermodynamics and kinetics of γ-valerolactone/ϵ-caprolactone

The general misconception that γ-lactones are not thermodynamically polymerizable has limited the development of all γ-lactone-based copolymers. A few studies have reported copolymerization of these five-membered cyclic esters with more reactive monomers, yet a systematic investigation of kinetics a...

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Detalles Bibliográficos
Autores principales: Gagliardi, Mariacristina, Bifone, Angelo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013151/
https://www.ncbi.nlm.nih.gov/pubmed/29927986
http://dx.doi.org/10.1371/journal.pone.0199231