Cargando…

Internal dynamics and guest binding of a sterically overcrowded host

Substituent control in self-assembled host systems allows for a fine-tuning of structure, dynamics and guest preference. Flat banana-shaped ligands L(1) assemble with Pd(ii) cations into the interpenetrated coordination cage dimer [3BF(4)@Pd(4)L(1)(8)], capable of sequential guest uptake. In contras...

Descripción completa

Detalles Bibliográficos
Autores principales: Löffler, Susanne, Lübben, Jens, Wuttke, Axel, Mata, Ricardo A., John, Michael, Dittrich, Birger, Clever, Guido H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013793/
https://www.ncbi.nlm.nih.gov/pubmed/30155116
http://dx.doi.org/10.1039/c6sc00985a