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Modulating the cobalt redox potential through imidazole hydrogen bonding interactions in a supramolecular biomimetic protein-cofactor model

A realistic model for the active site of histidine-on cobalamin@protein complexes is reported and studied under homogeneous and immobilized conditions. Analysis of lower ligand modulation and its influence on the properties of the biomimetic compound are presented. The cofactor attachment by a prote...

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Detalles Bibliográficos
Autores principales: Sonnay, Marjorie, Fox, Thomas, Blacque, Olivier, Zelder, Felix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6013808/
https://www.ncbi.nlm.nih.gov/pubmed/30155026
http://dx.doi.org/10.1039/c5sc04396d

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