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K⊂{[Fe(II)(Tp)(CN)(3)](4)[Co(III)((pz)Tp)](3)[Co(II)((pz)Tp)]}: a neutral soluble model complex of photomagnetic Prussian blue analogues
Straightforward access to a new cyanide-bridged {Fe(4)Co(4)} “molecular box” containing a potassium ion, namely K⊂{[Fe(II)(Tp)(CN)(3)](4)[Co(III)((pz)Tp)](3)[Co(II)((pz)Tp)]} (1) (with Tp and (pz)Tp = tris- and tetrakis(pyrazolyl)borate, respectively), is provided, alongside its full characterisatio...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6014070/ https://www.ncbi.nlm.nih.gov/pubmed/30155130 http://dx.doi.org/10.1039/c6sc01435f |