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[d]-Carbon–carbon double bond engineering in diazaphosphepines: a pathway to modulate the chemical and electronic structures of heteropines

We have designed and synthesized the first examples of 7-membered diazaphosphepines using phosphorus–amine (P–N) chemistry. Different from previous functional protocols of heteropines, the installation of π-conjugated substituents having diverse chemistries at the [d]-C[double bond, length as m-dash...

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Detalles Bibliográficos
Autores principales:	Ren, Yi, Sezen, Melda, Guo, Fang, Jäkle, Frieder, Loo, Yueh-Lin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6014086/ https://www.ncbi.nlm.nih.gov/pubmed/30155067 http://dx.doi.org/10.1039/c6sc00519e

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