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Post-synthetic modification of a macrocyclic receptor via regioselective imidazolium ring-opening
A facile post-synthetic modification of a tetracationic tetraimidazolium macrocycle, 1(4+) (i.e., the “Texas-sized” molecular box (cyclo[2](2,6-di(1H-imidazol-1-yl)pyridine)[2](1,4-dimethylenebenzene)), is described. Under mild basic conditions, ring-opening of the imidazolium moieties occurs. This...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6014093/ https://www.ncbi.nlm.nih.gov/pubmed/30155059 http://dx.doi.org/10.1039/c5sc04860e |