One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides

A one-step access to dithioacetal-α,α-diglycosides is reported. The synthetic strategy is based on the thioacetalization of aldehydes or ketones via highly stereoselective ring-opening of 1,6 anhydrosugars with bis(trimethylsilyl)sulfide.

Detalles Bibliográficos
Autores principales: Céspedes Dávila, Maria F., Schneider, Jérémy P., Godard, Amélie, Hazelard, Damien, Compain, Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017313/
https://www.ncbi.nlm.nih.gov/pubmed/29662042
http://dx.doi.org/10.3390/molecules23040914
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author Céspedes Dávila, Maria F.
Schneider, Jérémy P.
Godard, Amélie
Hazelard, Damien
Compain, Philippe
author_facet Céspedes Dávila, Maria F.
Schneider, Jérémy P.
Godard, Amélie
Hazelard, Damien
Compain, Philippe
author_sort Céspedes Dávila, Maria F.
collection PubMed
description A one-step access to dithioacetal-α,α-diglycosides is reported. The synthetic strategy is based on the thioacetalization of aldehydes or ketones via highly stereoselective ring-opening of 1,6 anhydrosugars with bis(trimethylsilyl)sulfide.
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spelling pubmed-60173132018-11-13 One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides Céspedes Dávila, Maria F. Schneider, Jérémy P. Godard, Amélie Hazelard, Damien Compain, Philippe Molecules Communication A one-step access to dithioacetal-α,α-diglycosides is reported. The synthetic strategy is based on the thioacetalization of aldehydes or ketones via highly stereoselective ring-opening of 1,6 anhydrosugars with bis(trimethylsilyl)sulfide. MDPI 2018-04-15 /pmc/articles/PMC6017313/ /pubmed/29662042 http://dx.doi.org/10.3390/molecules23040914 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Céspedes Dávila, Maria F.
Schneider, Jérémy P.
Godard, Amélie
Hazelard, Damien
Compain, Philippe
One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides
title One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides
title_full One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides
title_fullStr One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides
title_full_unstemmed One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides
title_short One-Pot, Highly Stereoselective Synthesis of Dithioacetal-α,α-Diglycosides
title_sort one-pot, highly stereoselective synthesis of dithioacetal-α,α-diglycosides
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6017313/
https://www.ncbi.nlm.nih.gov/pubmed/29662042
http://dx.doi.org/10.3390/molecules23040914
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